The self-assembly between C2-symmetric (methanol)6 or S6-symmetric (ethanol)6 cyclohexamers and paddle-wheel dinuclear copper units leads to unique 1D polymer chains

被引:13
|
作者
Benisvy, Laurent
Mutikainen, Ilpo
Quesada, Manuel
Turpeinen, Urho
Gamez, Patrick
Reedijk, Jan
机构
[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[2] Univ Helsinki, Dept Chem, Inorgan Chem Lab, Helsinki 00014, Finland
关键词
D O I
10.1039/b608220c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first crystallographic evidences of the theoretically suggested C-2-symmetric cyclohexameric form of liquid methanol and the S-6-symmetric cyclohexameric form of liquid ethanol are reported, trapped inside a hydrophilic pocket shielded by tert-butyl groups.
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页码:3723 / 3725
页数:3
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