Pure organic room-temperature phosphorescent N-allylquinolinium salts as anti-counterfeiting materials

被引:26
|
作者
Xiong, Qingxia [1 ,2 ]
Xu, Chao [4 ,5 ]
Jiao, Nianming [1 ,2 ]
Ma, Xiang [4 ,5 ]
Zhang, Yanqiang [1 ,3 ]
Zhang, Suojiang [1 ]
机构
[1] Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn,State Key Lab Multi, Beijing 100049, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China
[3] Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Henan, Peoples R China
[4] East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[5] East China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
基金
中国国家自然科学基金;
关键词
N-Allylquinoline; Room-temperature phosphorescence; Anti-counterfeiting; EMISSION; LUMINESCENCE; FLUORESCENCE; ENHANCEMENT; FILMS;
D O I
10.1016/j.cclet.2019.04.010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pure organic room-temperature phosphorescence (RTP) materials have been attracting much attention recently. Herein, we report a facile approach combining heavy atom effect and extemal solvent stimuli to realize RTP. N-Allylquinolinium bromide under 365 nm UV exhibited intense green RTP emission with response upon adding chloroform. This interesting phenomenon endowed N-allylquinolinium bromide great potential as an anti-counterfeiting material. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1387 / 1389
页数:3
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