Dehydrogenation of a tertiary amine-borane by a rhenium complex

被引：19

作者：

Muhammad, Sohail ^{[1
]}

Moncho, Salvador ^{[1
]}

Brothers, Edward N. ^{[1
]}

Bengali, Ashfaq A. ^{[1
]}

机构：

[1] Texas A&M Univ Qatar, Dept Chem, Doha, Qatar

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 44期

关键词：

FREE HYDROGEN-TRANSFER; LEWIS BASE ADDUCTS; TRANSITION-METAL; AMMONIA-BORANE; CATALYZED DEHYDROGENATION; DEHYDROCOUPLING REACTIONS; RUTHENIUM COMPLEXES; HYDRIDE TRANSFER; BOND ACTIVATION; COORDINATION;

D O I：

10.1039/c4cc01771d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of CpRe(CO)(3) in the presence of H3BNEt3 yields the trans-CpRe(CO)(2)(H)(2) complex. This preliminary finding presents a rare example of transition metal mediated dehydrogenation of a tertiary amine-borane and suggests that the abstracted hydrogens may be stored in the form of metal hydride complexes.

引用

页码：5874 / 5877

页数：4

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