Hybrid composites from poly[(4-vinylbenzyl)trimethylammonium chloride]-metal oxide using simultaneous radical polymerization/sol-gel synthesis

被引：7
|
作者：
Campos, Cristian H. [1 ]
Urbano, Bruno F. [2 ]
Rivas, Bernabe L. [2 ]
机构：
[1] Ctr Adv Polymer Res, Concepcion 4070412, Chile
[2] Univ Concepcion, Fac Chem, Dept Polymers, Concepcion 4070371, Chile
来源：
MATERIALS LETTERS | 2014年 / 131卷
关键词：
Hybrid materials; Sol-gel syntheses; Ammonium quaternary polymer metal-oxides; NANOPARTICLES; SYSTEMS; SURFACE;
D O I：
10.1016/j.matlet.2014.05.161
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This communication reports the preparation and characterization of poly(4-vinylbenzyl)-trimethylammonium chloride (PCIVBTA)-3-(trimethoxysilyl)propylmethacrylate (TMPM)-MxOy (M: Al, Ti or Zr) composites using a radical polymerization/sol-gel synthesis route. The results indicate that all of the materials form interpenetrating networks (IPNs) and that TMPM forms a bridge between the organic and inorganic networks. The polymer phase yield, with respect to the oxide, occurred in the following order: Al2O3 > TiO2 > ZrO2. The physico-chemical properties of the materials were dependent on the nature of the metal oxide that was incorporated in the network. All materials exhibited good thermal stability and morphologies that were typical for non-porous materials. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：198 / 202
页数：5
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