Enhancing formic acid dehydrogenation for hydrogen production with the metal/organic interface

被引：43

作者：

Wang, Hongli ^{[1
]}

Chi, Yue ^{[1
]}

Gao, Dawei ^{[1
]}

Wang, Zhili ^{[2
]}

Wang, Cong ^{[1
]}

Wang, Liying ^{[1
]}

Wang, Minggang ^{[1
]}

Cheng, Daowen ^{[1
]}

Zhang, Jingjing ^{[1
]}

Wu, Chen ^{[1
]}

Zhao, Zhankui ^{[1
]}

机构：

[1] Changchun Univ Technol, Coll Mat Sci & Engn, Minist Educ, Key Lab Adv Struct Mat, Changchun 130012, Jilin, Peoples R China

[2] Jilin Univ, Dept Mat Sci & Engn, Minist Educ, Key Lab Automobile Mat, Changchun 130022, Jilin, Peoples R China

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2019年 / 255卷

基金：

中国国家自然科学基金;

关键词：

Formic acid; Metal/organic interface; Hydrogen production; Heterogeneous catalyst; REDUCED GRAPHENE OXIDE; METAL-ORGANIC FRAMEWORK; ROOM-TEMPERATURE DEHYDROGENATION; ALLOY NANOPARTICLES; PALLADIUM NANOPARTICLES; EFFICIENT NANOCATALYST; SYNERGISTIC CATALYSIS; IN-SITU; GENERATION; DECOMPOSITION;

D O I：

10.1016/j.apcatb.2019.117776

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ultrafine and well-dispersed CrPd nanoparticles are successfully immobilized on 3-aminopropyl triethoxysilane functionalized monochlortriaziny beta-cyclodeztrin (M-beta-CD-A) by a facile wet-chemical method. Benefiting from the strong metal/organic interfacial interactions between the CrPd nanoparticles and M-beta-CD-A support, the Cr-0.4 Pd-0.6/M-beta-CD-A catalyst exhibits excellent catalytic activity towards formic acid dehydrogenation for hydrogen production, affording a high initial turn over frequency of 5771 mol H-2 mol Pd( )(-1)h(-1) without any additive at 323 K, which is much higher than those obtained for most of the reported noble metal catalysts under similar conditions. This work provides a promising lead for the design of efficient heterogeneous catalysts toward formic acid dehydrogenation for hydrogen production.

引用

页数：8

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