Cucurbiturils Substituted on the Methylene Bridge

被引：31

作者：

Gilberg, Laura ^{[1
,2
]}

Khan, Muhammad S. A. ^{[1
,2
]}

Enderesova, Marketa ^{[1
,2
]}

Sindelar, Vladimir ^{[1
,2
]}

机构：

[1] Masaryk Univ, RECETOX, Brno 62500, Czech Republic

[2] Masaryk Univ, Dept Chem, Brno 62500, Czech Republic

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 09期

关键词：

DERIVATIVES;

D O I：

10.1021/ol500828k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cucurbit[6]uril (CB[6]) with a substituent attached solely to one methylene bridge was prepared for the first time. The monosubstituted CB[6] undergoes self-assembly to form a cyclic tetramer in the solid state. The affinity of the monosubstituted CB[6] to a series of alkylammonium salts was measured revealing a minor effect of the substituent on the binding properties of the macrocycle.

引用

页码：2446 / 2449

页数：4

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