Synthesis of gold nanopartieles from an organometallic compound in supercritical carbon dioxide

被引：42
|
作者：
Esumi, K [1 ]
Sarashina, S
Yoshimura, T
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan
[2] Tokyo Univ Sci, Inst Colloid & Interface Sci, Shinjuku Ku, Tokyo 1628601, Japan
来源：
LANGMUIR | 2004年 / 20卷 / 13期
关键词：
D O I：
10.1021/la049415e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This article presents the synthesis of gold nanoparticles in a single-phase supercritical fluid carbon dioxide solvent. The gold nanoparticles were formed by the reduction of triphenylphosphine gold(I) perfluorooctanoate with dimethylamineborane. Transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-vis spectroscopy reveal the formation of gold nanoparticles of 1 nm in diameter. A high dispersion stability of the gold nanoparticles in supercritical carbon dioxide can be obtained by binding both triphenylphosphine and fluorocarbon ligands on the surface of the gold nanoparticles.
引用
收藏
页码：5189 / 5191
页数：3
相关论文
共 50 条
  • [1] Infusion of the organometallic compound into organic materials using supercritical carbon dioxide
    Nakanishi, T
    [J]. KOBUNSHI RONBUNSHU, 2001, 58 (12) : 710 - 713
  • [2] Elution of gold from activated carbon using supercritical carbon dioxide
    Otu, EO
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 1997, 32 (06) : 1107 - 1114
  • [3] Solubility of organometallic complexes in supercritical carbon dioxide: A review
    Teoh, Wen Hui
    Mammucari, Raffaella
    Foster, Neil R.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 724 : 102 - 116
  • [4] Deposition of gold films and nanostructures from supercritical carbon dioxide
    Cabañas, A
    Long, DP
    Watkins, JJ
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (10) : 2028 - 2033
  • [5] Kinetics of diffusion of organometallic compounds into polymers from solutions in supercritical carbon dioxide
    Sobol', EN
    Bagratashvili, VN
    Popov, VK
    Sobol', AE
    Said-Galiev, EE
    Nikitin, LN
    [J]. ZHURNAL FIZICHESKOI KHIMII, 1998, 72 (01): : 23 - 26
  • [6] Germanium Nanowire Synthesis from Fluorothiolate-Capped Gold Nanoparticles in Supercritical Carbon Dioxide
    Collins, Gillian
    Kolesnik, Maria
    Krstic, Vojislav
    Holmes, Justin D.
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (18) : 5235 - 5243
  • [7] Condensation and cleaning of an organometallic copper compound to/from porous low-dielectric constant thin films in supercritical carbon dioxide
    Kondoh, E.
    Ukai, E.
    Aruga, S.
    [J]. PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 5, NO 5, 2008, 5 (05): : 1219 - 1222
  • [8] Supercritical carbon dioxide elution of gold - Cyanide complex from activated carbon
    Otu, EO
    Wilson, JJ
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 2000, 35 (12) : 1879 - 1886
  • [9] Synthesis of biodiesel in supercritical alcohols and supercritical carbon dioxide
    Varma, Mahesh N.
    Deshpande, Parag A.
    Madras, Giridhar
    [J]. FUEL, 2010, 89 (07) : 1641 - 1646
  • [10] Synthesis of polyimides in supercritical carbon dioxide
    Said-Galiyev, EE
    Vygodskii, YS
    Nikitin, LN
    Vinokur, RA
    Gallyamov, MO
    Pototskaya, IV
    Kireev, VV
    Khokhlov, AR
    Schaumburg, K
    [J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2003, 26 (02): : 147 - 156
12345