Two 3D metal(II)-organic coordination polymers constructed by semi-rigid imidazolium carboxylate ligand: synthesis, crystal structure and property

被引：3
|
作者：
Lu, Jiu-Fu [1 ]
Liu, Mei-Ling [1 ]
Zhao, Cai-Bin [1 ]
Huang, Pei [1 ]
Gao, Yan-Hong [1 ]
Zheng, Nan [1 ]
Wang, Qin [1 ]
Jin, Ling-Xia [1 ]
Yu, Xiao-Hu [1 ]
Ge, Hong-Guang [1 ]
机构：
[1] Shaanxi Univ Technol, Coll Chem & Environm Sci, Shaanxi Key Lab Catalysis, Hanzhong, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2020年 / 51卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; diamondoid frameworks; gas adsorption; semi-rigid;
D O I：
10.1080/24701556.2020.1835971
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two metal coordination polymers, namely {[Co(MIBA)(2)]center dot 2H(2)O}(n) (SNUT-3) and {[Cu(MIBA)(2)]center dot 2H(2)O}(n) (SNUT-4), where HMIBA = 4-(1H-2-methylimidazol-1-yl)benzoic acid, were prepared by hydrothermal methods. Single-crystal X-ray analysis revealed that the structure of SNUT-3 exhibits a 3D -> 3D fourfold interpenetrating structure with diamondoid frameworks, while SNUT-4 shows a 2D + 2D -> 3D inclined polycatenation structure. The gas adsorption property of SNUT-3 and photocatalytic activity of SNUT-4 for the degradation of Rhodamine B has been explored.
引用
收藏
页码：1323 / 1330
页数：8
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