A new three-dimensional cobalt phosphate:: Co5(OH2)4(HPO4)2(PO4)2

被引：9
|
作者：
Han, Zhangang
Tian, Aixiang
Peng, Jun [1 ]
Zhai, Xueliang
机构：
[1] Hebei Normal Univ, Fac Chem, Shijiazhuang 050016, Hebei, Peoples R China
[2] NE Normal Univ, Fac Chem, Changchun 130024, Jilin, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2006年 / 179卷 / 10期
关键词：
cobalt; phosphate; metal-phosphate; magnetism;
D O I：
10.1016/j.jssc.2006.05.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A three-dimensional (3D) cobalt phosphate: Co-5(OH2)(4)(HPO4)(2)(PO4)(2) (1), has been synthesized by hydrothermal reaction and characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and magnetic techniques. The title compound is a template free cobalt phosphate. Compound 1 exhibits a complex net architecture based on edge- and corner-sharing Of CoO6 and PO4 polyhedra. The magnetic susceptibility measurements indicated that the title compound obeys Curie-Weiss behavior down to a temperature of 17 K at which an antiferromagnetic phase transition occurs. (c) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码：3209 / 3213
页数：5
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