High-Temperature CO2 Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects

被引:285
|
作者
Song, Yuefeng [1 ,2 ]
Zhang, Xiaomin [1 ]
Xie, Kui [3 ]
Wang, Guoxiong [1 ]
Bao, Xinhe [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis,CAS Ctr Excellence Nanosc, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
CO2; electrolysis; perovskites; solid oxide electrolysis cells; OXYGEN ELECTRODES; CARBON-DIOXIDE; FUEL-CELL; ELECTROCHEMICAL PERFORMANCE; INTERMEDIATE-TEMPERATURE; STEAM ELECTROLYSIS; ELECTROCATALYTIC REDUCTION; ELIMINATING DEGRADATION; RUDDLESDEN-POPPER; SYNGAS PRODUCTION;
D O I
10.1002/adma.201902033
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-temperature CO2 electrolysis in solid-oxide electrolysis cells (SOECs) could greatly assist in the reduction of CO2 emissions by electrochemically converting CO2 to valuable fuels through effective electrothermal activation of the stable C(sic)O bond. If powered by renewable energy resources, it could also provide an advanced energy-storage method for their intermittent output. Compared to low-temperature electrochemical CO2 reduction, CO2 electrolysis in SOECs at high temperature exhibits higher current density and energy efficiency and has thus attracted much recent attention. The history of its development and its fundamental mechanisms, cathode materials, oxygen-ion-conducting electrolyte materials, and anode materials are highlighted. Electrode, electrolyte, and electrode-electrolyte interface degradation issues are comprehensively summarized. Fuel-assisted SOECs with low-cost fuels applied to the anode to decrease the overpotential and electricity consumption are introduced. Furthermore, the challenges and prospects for future research into high-temperature CO2 electrolysis in SOECs are included.
引用
收藏
页数:18
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