Constructing mainstay-body structure in heterocyclic aramid fiber to simultaneously improve tensile strength and toughness

被引:30
|
作者
Yang, Cheng [1 ]
Wu, Hang [2 ]
Dai, Yu [1 ]
Zhang, Dajie [1 ]
Xu, Ruopei [1 ]
Luo, Longbo [1 ]
Liu, Xiangyang [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat & Engn, Chengdu 610065, Peoples R China
[2] Beijing Special Vehicle Inst, Beijing 100072, Peoples R China
基金
中国国家自然科学基金;
关键词
Heterocyclic aramid fiber; Ultra-high molecular weight; Relaxation time; Elongation at break; Tensile strength; Mainstay-body structure; MECHANICAL-PROPERTIES; HIGH-MODULUS; EXTRUSION; COMPOSITE; POLYAMIDE; UNITS; PIPD;
D O I
10.1016/j.compositesb.2020.108411
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High-performance polymer fibers have broad applications in composites due to high strength and excellent toughness. However, the enhancement in tensile strength often results in a decrease in elongation at break, and simultaneous increase of strength and toughness is still challenging for aramid fiber. Herein, an effective method based on relaxation time theory is proposed to simultaneously enhance the tensile strength and elongation at break for heterocyclic aramid fiber. Ultra-high molecular weight heterocyclic aramid (HMPBIA) was added in the heterocyclic aramid (PBIA) spinning dope to prepare fibers. The structure evolution of fiber is studied in detail combining with experiment and simulation. Results of Molecular Dynamics simulations prove that HMPBIA acts as a role of mainstay by maintaining straight chain conformation in highly oriented fibers. This unique mainstay-body structure weaken slippage between molecular chains when the fiber is subject to tension. Further characterizations by small angle X-ray scattering (SAXS) and scanning electron microscope (SEM) confirm the formation of mainstay-body structure in the fiber, which improves tensile strength and elongation at break by 17.7% and 16.7%, respectively.
引用
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页数:10
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