Efficient Oxidation of Sulfides to the Sulfoxides Using Zirconium (IV) Chloride, Sodium Nitrite and Catalytic Amounts of Bromide Ion as a Novel Oxidizing Media

被引：39

作者：

Ghorbani-Choghamarani, Arash ^{[1
]}

Goudarziafshar, Hamid ^{[1
]}

Nikoorazm, Mohsen ^{[1
]}

Yousefi, Somaieh ^{[1
]}

机构：

[1] Ilam Univ, Fac Sci, Dept Chem, Ilam, Iran

来源：

LETTERS IN ORGANIC CHEMISTRY | 2009年 / 6卷 / 04期

关键词：

Sulfoxides; Homoselectivity; Zirconium chloride (ZrCl(4)); Sodium nitrite (NaNO(2)); SOLVENT-FREE CONDITIONS; AQUEOUS HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; ASYMMETRIC OXIDATION; PUMMERER REARRANGEMENT; MOLECULAR-OXYGEN; SULFONES; REAGENT; ACID; NITRATE;

D O I：

10.2174/157017809788489882

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chemo and homoselective catalytic oxidation of sulfides has been developed. A variety of aliphatic and aromatic sulfides are subjected to the sulfoxidation reaction using ZrCl(4), NaNO(2) and catalytic amounts of KBr or NaBr in the presence of wet SiO(2) (50% w/w) in acetonitrile at room temperature.

引用

页码：335 / 339

页数：5

共 20 条

[1] Catalytic oxidation of sulfides to sulfoxides using aluminium hydrogen sulfate, sodium nitrite and catalytic amounts of metal bromide
A. Ghorbani-Choghamarani
J. Zeinivand
[J]. Journal of the Iranian Chemical Society, 2010, 7 : 190 - 194
[2] Catalytic Oxidation of Sulfides to Sulfoxides Using Aluminium Hydrogen Sulfate, Sodium Nitrite and Catalytic Amounts of Metal Bromide
Ghorbani-Choghamarani, A.
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[J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2010, 7 (01) : 190 - 194
[3] Aluminium Nitrate/Silica Sulfuric Acid/Bromide Ion: As an Effective and Catalytic Oxidizing Media for the Selective Oxidation of Sulfides to Sulfoxides
Ghorbani-Choghamarani, Arash
Goudarziafshar, Hamid
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Soltani, Jinoos
[J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2008, 55 (06) : 1191 - 1194
[4] Ferric nitrate in the presence of catalytic amounts of KBr or NaBr: an efficient and homoselective catalytic media for the selective oxidation of sulfides to sulfoxides
Kamal Amani
Mohammad Ali Zolfigol
Arash Ghorbani-Choghamarani
Maryam Hajjami
[J]. Monatshefte für Chemie - Chemical Monthly, 2009, 140 : 65 - 68
[5] Ferric nitrate in the presence of catalytic amounts of KBr or NaBr: an efficient and homoselective catalytic media for the selective oxidation of sulfides to sulfoxides
Amani, Kamal
Zolfigol, Mohammad Ali
Ghorbani-Choghamarani, Arash
Hajjami, Maryam
[J]. MONATSHEFTE FUR CHEMIE, 2009, 140 (01): : 65 - 68
[6] A Novel Catalytic Method for the Oxidation of Sulfides to Sulfoxides with Silica Sulfuric Acid and Sodium Nitrite in the Presence of KBr and/or NaBr as Catalyst
Goudarziafshar, Hamid
Ghorbani-Choghamarani, Arash
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[J]. CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (09) : 1801 - 1804
[7] Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr
Zolfigol, Mohammad Ali
Amani, Kamal
Hajjami, Maryam
Ghorbani-Choghamarani, Arash
[J]. MONATSHEFTE FUR CHEMIE, 2008, 139 (08): : 895 - 899
[8] Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr
Mohammad Ali Zolfigol
Kamal Amani
Maryam Hajjami
Arash Ghorbani-Choghamarani
[J]. Monatshefte für Chemie - Chemical Monthly, 2008, 139
[9] Catalytic oxidation of sulfides to sulfoxides using sodium perborate and/or sodium percarbonate and silica sulfuric acid in the presence of KBr
Habibi, Davood
Zolfigol, Mohammad Ali
Safaiee, Malihe
Shamsian, Atefeh
Ghorbani-Choghamarani, Arash
[J]. CATALYSIS COMMUNICATIONS, 2009, 10 (08) : 1257 - 1260
[10] Guanidinium Nitrate/Silica Sulfuric Acid/Ammonium Bromide as an Effective, Viable and Metal-free Catalytic Media for the Selective Oxidation of Sulfides to the Sulfoxides
Nikoorazm, Mohsen
Ghorbani-Choghamarani, Arash
Goudarziafshar, Hamid
[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2009, 30 (12) : 3120 - 3122

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