Synthesis and properties of upper rim Schiff base calix[4]arenes

被引：21
|
作者：
Guo, TD [1 ]
Zheng, QY [1 ]
Yang, LM [1 ]
Huang, ZT [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2000年 / 36卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Schiff base; calixarene; upper rim; complexation; transition metals;
D O I：
10.1023/A:1008006600696
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and properties of upper rim Schiff base calix[4]arenes are described in this article. Tetrakis-p-bromomethylcalix[4]arene ( 1) reacts with hexamethylenetetramine to give tetrakis-p-formylcalix[4]arene ( 2) in high yield. Then upper rim Schiff base calix[4]arenes 3 can be easily synthesized by 2 reacting with appropriate alkylamines. The complexation ability of 3 toward transition metals Pb2+, Cu2+ and Co2+ was studied by UV-VIS spectrophotometry.
引用
收藏
页码：327 / 333
页数：7
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