EC-STM Study of Two-Dimensional Complex Adlayer Directly Formed on Au(111)

被引：0
|
作者：
Yoshimoto, Soichiro [1 ,2 ]
Nishiyama, Katsuhiko [2 ,3 ]
机构：
[1] Kumamoto Univ, Prior Org Innovat & Excellence, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan
[2] Kumamoto Inst Photo Electoorgan Phoen, Higashi Ku, Kumamoto 8620901, Japan
[3] Kumamoto Univ, Grad Sch Sci & Technol, Chuo Ku, Kumamoto 8608555, Japan
来源：
ELECTRODEPOSITION FUNDAMENTALS AND NEW MATERIALS (GENERAL) - 222ND ECS MEETING/PRIME 2012: DIETER M. KOLB MEMORIAL SYMPOSIUM | 2013年 / 50卷 / 52期
基金：
日本科学技术振兴机构;
关键词：
ORDERED ARRAYS; METAL-IONS; SURFACES; NANOSTRUCTURES; TERPYRIDINE; PORPHYRINS; LIGANDS; SYSTEMS;
D O I：
10.1149/05052.0035ecst
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Redox-active adlayers consisting of 4', 4 ''''-(1,4-phenylene) bis(2,2':6',2 ''-terpyridine) ligand and Co2+ and/or Fe2+, were prepared on a Au(111) surface by a stepwise coordination method. The obtained adlayers produced a well-defined, stable redox wave associated with Co2+ and/or Fe2+ coordinated to 4',4 ''''-(1,4-phenylene) bis(2,2':6',2 ''-terpyridine). It was found that the ability to coordinate with PTPy adlayer formed on Au(111) was clearly dependent on the metal ions.
引用
收藏
页码：35 / 40
页数：6
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