Coordination polymers constructed from transition metal ions and organic N-containing heterocyclic ligands: Crystal structures and microporous properties

被引:140
|
作者
Noro, Shin-ichiro [1 ]
Kitagawa, Susumu [2 ]
Akutagawa, Tomoyuki [1 ]
Nakamura, Takayoshi [1 ]
机构
[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0010020, Japan
[2] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
关键词
Coordination polymer; Metal ion; Organic N-containing heterocyclic ligands; Crystal structure; Microporous properties; Dynamic framework; COPPER(II) BENZOATE-PYRAZINE; LOW-TEMPERATURE OXIDATION; SELECTIVE GUEST BINDING; X-RAY-DIFFRACTION; ADSORPTION PROPERTIES; HYDROGEN STORAGE; SORPTION PROPERTIES; MICROWAVE SYNTHESIS; CLATHRATE-FORMATION; PHASE-TRANSITION;
D O I
10.1016/j.progpolymsci.2008.09.002
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The chemistry of coordination polymers has been extensively advanced in recent decades, producing various architectures that are rationally constructed from a variety of molecular building blocks and interactions between them. Researchers have worked to create a diverse range of coordination frameworks and have raised the structural chemistry to a mature level. The next challenge is to explore their chemical and physical functionalities, which are associated with the microporous properties of frameworks. This review focuses on crystal structures and microporous properties of coordination polymers containing organic N-containing heterocyclic molecules as bridging ligands. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:240 / 279
页数:40
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