We investigate the elastic and anelastic structure of the lowermost mantle at the western edge of the Pacific large low shear velocity province (LLSVP) by inverting a collection of S and ScS waveforms. The transverse component data were obtained from F-net for 31 deep earthquakes beneath Tonga and Fiji, filtered between 12.5 and 200 s. We observe a regional variation of S and ScS arrival times and amplitude ratios, according to which we divide our region of interest into three subregions. For each of these subregions, we then perform 1-D (depth-dependent) waveform inversions simultaneously for radial profiles of shear wave velocity (V-S) and seismic quality factor (Q). Models for all three subregions show low V-S and low Q structures from 2000 km depth down to the core-mantle boundary. We further find that V-S and Q in the central subregion, sampling the Caroline plume, are substantially lower than in the surrounding regions, whatever the depth. In the central subregion, V-S-anomalies with respect to PREM (dV(S)) and Q are about -2.5 per cent and 216 at a depth of 2850 km, and -0.6 per cent and 263 at a depth of 2000 km. By contrast, in the two other regions, dV(S) and Q are -2.2 per cent and 261 at a depth of 2850 km, and -0.3 per cent and 291 at a depth of 2000 km. At depths greater than similar to 2500 km, these differences may indicate lateral variations in temperature of similar to 100 K within the Pacific LLSVP. At shallower depths, they may be due to the temperature difference between the Caroline plume and its surroundings, and possibly to a small fraction of iron-rich material entrained by the plume.