Efficient enantioselective hydrosilylation of aryl ketones catalyzed by a chiral BINAP-copper(I) catalyst-phenyl(methyl)silane system

被引：58
|
作者：
Issenhuth, Jean Thomas [1 ]
Dagorne, Samuel [1 ]
Bellemin-Laponnaz, Stephane [1 ]
机构：
[1] Univ Strasbourg, Inst Le Bel, Lab DECOMET, UMR 7177, F-67000 Strasbourg, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2006年 / 348卷 / 14期
关键词：
asymmetric catalysis; copper; hydride; hydrosilylation;
D O I：
10.1002/adsc.200606152
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The Cu(I)-chiral diphosphine (BINAP) system was found to efficiently catalyze the hydrosilylation of aryl alkyl ketones with excellent enantioselectivities by using phenyl(methyl)silane as stoichiometric hydride source.
引用
收藏
页码：1991 / 1994
页数：4
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