Direct hydro-liquefaction of sawdust in petroleum ether and comprehensive bio-oil products analysis

The effect of temperature, time, hydrogen pressure and amount of catalyst on production distribution and the bio-oil yield obtained from the direct liquefaction of sawdust in the petroleum ether (60-90 degrees C) are investigated. The highest sawdust conversion obtained was 72.32% with a bio-oil yield of 47.69% were obtained at 370 degrees C, 40 min and 5wt.% catalyst content with the initial H-2 pressure of 3.0 MPa. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approach was utilized to analyze the non-volatile fraction. In this study, the composition of bio-oil could be analyzed in an unprecedented detail through a combination of GC-MS and FT-ICR MS techniques. (C) 2014 Elsevier Ltd. All rights reserved.