The Biosorption of Phenol from Petroleum Refinery Wastewater Using Spent Waste Biomass

被引：9
|
作者：
Younis, Sh. A. [1 ]
El-Gendy, N. Sh. [1 ]
El-Azab, W. I. [1 ]
Moustafa, Y. M. [1 ]
Hashem, A. I. [2 ]
机构：
[1] Egyptian Petr Res Inst, Cairo 11727, Egypt
[2] Ain Shams Univ, Fac Sci, Dept Chem, Cairo, Egypt
来源：
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS | 2014年 / 36卷 / 23期
关键词：
biosorption; equilibrium isotherm; kinetic study; phenol; spent waste biomass; thermodynamic analyses; AQUEOUS-SOLUTION; EQUILIBRIUM ISOTHERM; RESIDUE-MANAGEMENT; RICE STRAW; BASIC DYE; ADSORPTION; REMOVAL; KINETICS; RECOVERY; HUSK;
D O I：
10.1080/15567036.2013.855845
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
This work investigates the potentiality of application of spent waste biomass (yeast Saccharomyces cerevisiae, rice straw, and sugarcane bagasse) from bioethanol production process as low-cost biosorbents for removal of phenol from petroleum refinery wastewater. Batch adsorption studies were carried out under varying experimental conditions of contact time, initial phenol concentration, and operational temperature. Rice straw showed better affinity towards phenol than sugarcane bagasse, while S. cerevisiae did not express any biosorption capacity. The biosorption process on rice straw or sugarcane bagasse was fast and the time to reach equilibrium was found to be 150 min. Kinetic studies showed that biosorption follows the pseudo-second order rate expression. The results were better described by the Langmuir isotherm model than the Freundlich and Temkin isotherm models. The calculated heat of adsorption indicated that the biosorption process is taking place by chemical adsorption and has an endothermic nature.
引用
收藏
页码：2566 / 2578
页数：13
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