Communication: A scaling approach to anomalous diffusion

被引:23
|
作者
Kneller, Gerald R. [1 ,2 ,3 ]
机构
[1] CNRS, Ctr Biophys Mol, F-45071 Orleans, France
[2] Synchrotron Soleil, F-91192 Gif Sur Yvette, France
[3] Univ Orleans, F-45067 Orleans, France
来源
JOURNAL OF CHEMICAL PHYSICS | 2014年 / 141卷 / 04期
关键词
MEMORY FUNCTION; EQUATION; MOTION; MODELS; HEAT;
D O I
10.1063/1.4891357
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The paper presents a rigorous derivation of the velocity autocorrelation function for an anomalously diffusing slow solute particle in a bath of fast solvent molecules. The result is obtained within the framework of the generalized Langevin equation and uses only scaling arguments and identities which are based on asymptotic analysis. It agrees with the velocity autocorrelation function of an anomalously diffusing Rayleigh particle whose dynamics is described by a fractional Ornstein-Uhlenbeck process in velocity space. A simple semi-analytical example illustrates under which conditions the latter model is appropriate. (C) 2014 AIP Publishing LLC.
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页数:4
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