Electrochemical determination of nitrite in water samples using a glassy carbon electrode modified with didodecyldimethylammonium bromide

被引:31
|
作者
Zhang, Ying [1 ]
Luo, Liqiang [1 ]
Ding, Yaping [1 ]
Li, Li [1 ]
机构
[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
基金
中国国家自然科学基金;
关键词
Modified electrode; Surfactant; Didodecyldimethylammonium bromide; Nitrite determination; ELECTROCATALYTIC OXIDATION; COMPOSITE FILM; ASCORBIC-ACID; REDUCTION; NITRATE; SENSOR; MEMBRANES; BEHAVIOR;
D O I
10.1007/s00604-009-0232-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The oxidative electrochemistry of nitrite was investigated using a glassy carbon electrode modified with surfactants such as didodecyldimethylammonium bromide (DDAB), Tween-80, and sodium dodecylbenzenesulfonate, respectively. Nitrite oxidation proceeds best in the presence of DDAB. The electrode exhibited good sensitivity and fast response, with a linear dynamic range between 1.0 and 80 mu M of nitrite, and a sensitivity of 0.04 A mu A center dot A mu M-1. The electrode was successfully applied to the determination of nitrite in spiked real water samples.
引用
收藏
页码:123 / 128
页数:6
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