Direction Control of Oriented Self-Assembly for 1D, 2D, and 3D Microarrays of Anisotropic Rectangular Nanoblocks

被引：71
|
作者：
Nakagawa, Yoshitaka [1 ]
Kageyama, Hiroyuki [1 ]
Oaki, Yuya [1 ]
Imai, Hiroaki [1 ]
机构：
[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 10期
基金：
日本科学技术振兴机构;
关键词：
LITHIUM-ION BATTERIES; CAPACITY ANODE MATERIAL; STRUCTURAL-CHARACTERIZATION; MAGNETIC-PROPERTIES; NANOCUBES; SUPERLATTICES; MN3O4; NANOPARTICLES; NANOCRYSTALS;
D O I：
10.1021/ja410183q
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Micrometric linear chains (1D arrays), monolayers (2D arrays), and superstructures (3D arrays) of anisotropic Mn3O4 nanocuboids were selectively produced by oriented self-assembly through evaporation of a dispersion. The ID arrays were basically formed on a substrate via oriented self-assembly of the rectangular crystals in the < 100 > direction. The 2D and 3D microarrays were obtained by adjusting the particle concentration of the dispersion. The [001] direction of tetragonal crystal was controlled to be parallel and perpendicular to the substrate by changing the polarity of the medium.
引用
收藏
页码：3716 / 3719
页数：4
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