CdS-mesoporous ZnS core-shell particles for efficient and stable photocatalytic hydrogen evolution under visible light

被引:383
|
作者
Xie, Ying Peng [1 ]
Yu, Zong Bao [1 ]
Liu, Gang [1 ]
Ma, Xiu Liang [1 ]
Cheng, Hui-Ming [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
关键词
HIGH QUANTUM EFFICIENCY; HOLLOW SPHERES; H-2; EVOLUTION; PT-PDS/CDS; COCATALYSTS; DYNAMICS; PHOTOLUMINESCENCE; PHOTOREDUCTION; NANOCRYSTALS; SEPARATION;
D O I
10.1039/c3ee43750g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A mesoporous ZnS shell is in situ grown on a CdS core through a one-pot surfactant-free hydrothermal route. Due to the mesoporous ZnS shell and the unique spatial distribution of the photoexcited charge carriers in the CdS-ZnS core-shell particles, the hydrogen evolution rate over CdS-ZnS is 169 and 56 times higher than that of ZnS and CdS under visible light, respectively. Moreover, the core-shell particles show excellent photocatalytic stability over 60 h.
引用
收藏
页码:1895 / 1901
页数:7
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