Excess molar enthalpies for ternary mixtures containing [emim][BF4], cyclic amides and cyclic ketones

被引：3

作者：

Sharma, V. K. ^{[1
]}

Kataria, J. ^{[1
]}

Solanki, S. ^{[1
]}

机构：

[1] Maharshi Dayanand Univ, Dept Chem, Rohtak 124001, Haryana, India

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2016年 / 123卷 / 02期

关键词：

1-Ethyl-3-methylimidazolium tetrafluoroborate; 1-Methyl pyrrolidin-2-one; Density; Excess molar enthalpy; Interaction energy parameter; BINARY-LIQUID MIXTURES; THERMODYNAMIC PROPERTIES; 1-ETHYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE; IONIC LIQUIDS; PLUS ETHANOL; RELATIVE PERMITTIVITIES; MOLECULAR-INTERACTIONS; VOLUMETRIC PROPERTIES; PHYSICAL-PROPERTIES; TOPOLOGICAL ASPECTS;

D O I：

10.1007/s10973-015-5033-y

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The excess molar enthalpies, , data of ternary 1-ethyl-3-methylimidazolium tetrafluoroborate (1) + pyrrolidin-2-one or 1-methyl pyrrolidin-2-one (2) + cyclopentanone or cyclohexanone (3) mixtures have been measured at 298.15 K and 0.1 M Pa using microdifferential scanning calorimeter. The values of [emim][BF4] (1) + 2-Py (2) + cyclopentanone or cyclohexanone (3) are endothermic, while those for [emim][BF4] (1) + NMP (2) + cyclopentanone or cyclohexanone (3) mixtures are negative over entire composition of x (1) and x (2). The observed data of have been investigated in terms of Graph and Prigogine-Flory-Patterson theories. The results indicate that values estimated by Graph theory compare well with experimental values.

引用

页码：1571 / 1582

页数：12

共 50 条

[1] Excess molar enthalpies for ternary mixtures containing [emim][BF4], cyclic amides and cyclic ketones
V. K. Sharma
J. Kataria
S. Solanki
Journal of Thermal Analysis and Calorimetry, 2016, 123 : 1571 - 1582
[2] Excess Molar Enthalpies for Binary and Ternary Mixtures Containing Cyclic Ethers, Lactam and Cyclic Ketones
Sunita Malik
Heena Gupta
Dimple Sharma
Vinod Kumar Sharma
Journal of Solution Chemistry, 2017, 46 : 1639 - 1657
[3] Excess Molar Enthalpies for Binary and Ternary Mixtures Containing Cyclic Ethers, Lactam and Cyclic Ketones
Malik, Sunita
Gupta, Heena
Sharma, Dimple
Sharma, Vinod Kumar
JOURNAL OF SOLUTION CHEMISTRY, 2017, 46 (08) : 1639 - 1657
[4] Excess molar enthalpies for [Bmmim][BF4] + [Bmim][BF4] or [Emim][BF4] + cyclopentanone or cyclohexanone mixtures
Gupta, Heena
Malik, Sunita
Sharma, Vinod Kumar
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2019, 136 (03) : 1383 - 1394
[5] Excess molar enthalpies for [Bmmim][BF4] + [Bmim][BF4] or [Emim][BF4] + cyclopentanone or cyclohexanone mixtures
Heena Gupta
Sunita Malik
Vinod Kumar Sharma
Journal of Thermal Analysis and Calorimetry, 2019, 136 : 1383 - 1394
[6] Excess heat capacities of (binary + ternary) mixtures containing [emim][BF4] and organic liquids
Sharma, V.K.
Bhagour, S.
Solanki, S.
Sharma, D.
Journal of Chemical Thermodynamics, 2014, 79 : 19 - 32
[7] Topological and thermodynamic investigations of ternary mixtures containing cyclic ether: Excess molar enthalpies
Jangra, S. K.
Yadav, J. S.
Saini, N.
Sharma, D.
Sharma, V. K.
JOURNAL OF MOLECULAR LIQUIDS, 2011, 162 (03) : 122 - 128
[8] Excess heat capacities of (binary + ternary) mixtures containing [emim][BF4] and organic liquids
Sharma, V.K.
Bhagour, S.
Solanki, S.
Sharma, D.
Journal of Chemical Thermodynamics, 2014, 79 : 19 - 32
[9] Thermodynamic investigations of excess heat capacities of ternary liquid mixtures containing [Bmmim][BF4] + [Bmim][BF4] or [Emim][BF4] + cyclopentanone or cyclohexanone
Heena Gupta
Sunita Malik
Masta Chandrasekhar
Vinod Kumar Sharma
Journal of Thermal Analysis and Calorimetry, 2018, 131 : 1653 - 1669
[10] Thermodynamic investigations of excess heat capacities of ternary liquid mixtures containing [Bmmim][BF4] + [Bmim][BF4] or [Emim][BF4] + cyclopentanone or cyclohexanone
Gupta, Heena
Malik, Sunita
Chandrasekhar, Masta
Sharma, Vinod Kumar
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 131 (02) : 1653 - 1669

← 1 2 3 4 5 →