Perfluorovinyl-metal derivatives: A new one-pot synthesis

被引：38
|
作者：
Banger, KK [1 ]
Brisdon, AK [1 ]
Gupta, A [1 ]
机构：
[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 01期
关键词：
D O I：
10.1039/a605732b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The one-pot reaction of the CFC replacement 1,1,1,2-tetrafluoroethane (CF3CFH2, HFC-134a) with 2 equiv. of butyllithium in diethyl ether at -78 degrees C followed by the addition of main-group or transition-metal halides results in good yields of the corresponding metal-perfluorovinyl compounds of high purity.
引用
收藏
页码：139 / 140
页数：2
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