Preparation of vinylsilanes through the reaction of polyhalides with α-halogen substituted allylsilanes catalyzed by copper(I) chloride

被引：8

作者：

Mitani, M ^{[1
]}

Masuda, M ^{[1
]}

Inoue, A ^{[1
]}

机构：

[1] Shinshu Univ, Fac Engn, Dept Chem & Mat Engn, Wakasato, Nagano 3808553, Japan

来源：

SYNLETT | 2004年 / 07期

关键词：

addition reaction; silicon; copper catalysis; dehalogenation; carbon-carbon double bond;

D O I：

10.1055/s-2004-825579

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(1-Halo-2-propenyl)trimethylsilanes underwent the addition of polyhalides or alpha-haloesters under catalysis by the copper(l) ethanolamine or N,N,N',N'-tetramethylethylenediamine complex to bring about vinylsilane derivatives through dehalogenation accompanying the migration of the carbon-carbon double bond.

引用

页码：1227 / 1230

页数：4

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