Organo-Iodine(III)-Catalyzed Oxidative Phenol-Arene and Phenol-Phenol Cross-Coupling Reaction

被引：92

作者：

Morimoto, Koji ^{[1
,2
]}

Sakamoto, Kazuma ^{[1
]}

Ohshika, Takao ^{[1
]}

Dohi, Toshifumi ^{[1
]}

Kita, Yasuyuki ^{[1
,2
]}

机构：

[1] Ritsumeikan Univ, Coll Pharmaceut Sci, 1-1-1 Nojihigashi, Shiga 5258577, Japan

[2] Ritsumeikan Univ, Res Org Sci & Technol, 1-1-1 Nojihigashi, Shiga 5258577, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 11期

基金：

日本学术振兴会;

关键词：

biaryls; cross-coupling; homogenous catalysis; iodine; oxidation; HYPERVALENT IODINE REAGENTS; ORTHO-ARYLATION; CHIRAL RECOGNITION; FACILE SYNTHESIS; METAL; 2-NAPHTHOLS; DERIVATIVES; ACID; NAPHTHOLS; BINOL;

D O I：

10.1002/anie.201511007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct oxidative coupling reaction has been an attractive tool for environmentally benign chemistry. Reported herein is that the hypervalent iodine catalyzed oxidative metal-free cross-coupling reaction of phenols can be achieved using Oxone as a terminal oxidant in 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP). This method features a high efficiency and regioselectivity, as well as functional-group tolerance under very mild reaction conditions without using metal catalysts.

引用

页码：3652 / 3656

页数：5

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