Contact Angle Hysteresis Generated by Strong Dilute Defects

被引:165
|
作者
Reyssat, Mathilde [1 ]
Quere, David [1 ]
机构
[1] ESPCI, CNRS, UMR 7636, F-75005 Paris, France
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 12期
关键词
ULTRAHYDROPHOBIC SURFACES; SOLID-SURFACES; WATER; MODEL; HYDROPHOBICITY; WETTABILITY; DROPS; LINE;
D O I
10.1021/jp8066876
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Water on solid decorated with hydrophobic defects (such as micropillars) often stays at the top of the defects in a so-called fakir state, which explains the superhydrophobicity observed in such case, provided that the density of defects is small enough. Here we show that this situation provides an ideal frame for studying the contact angle hysteresis; the phase below the liquid is "perfect" and slippery (it is air), contrasting with pillars' tops whose edges form strong pining sites for the contact line. This model system thus allows us to study the hysteresis as a function of the density of defects and to compare it to the classical theory by Joanny and de Gennes, which is based on very similar hypothesis.
引用
收藏
页码:3906 / 3909
页数:4
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