Cobalt-catalyzed intramolecular Heck-type reaction of 6-halo-1-hexene derivatives

被引：86
|
作者：
Fujioka, T [1 ]
Nakamura, T [1 ]
Yorimitsu, H [1 ]
Oshima, K [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan
来源：
ORGANIC LETTERS | 2002年 / 4卷 / 13期
关键词：
D O I：
10.1021/ol0261128
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of 6-iodo-1-hexene derivatives with trimethylsilylmethyl Grignard reagent in the presence of CoCl2(dppb) in refluxing THF affords Heck-type products, methylenecyclopentanes, in good yields.
引用
收藏
页码：2257 / 2259
页数：3
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