[bmIm]OH catalyzed hetero-cyclisation of o-halobenzoic acid and alkyne: A green approach to synthesize isocoumarins

被引:20
|
作者
Waseem, Malik A. [1 ]
Abumandi, Shireen Afaf A. [1 ]
Srivastava, Arjita [1 ]
Srivastava, Anjali [1 ]
Rahila [1 ]
Siddiqui, I. R. [1 ]
机构
[1] Univ Allahabad, Dept Chem, Lab Green Synth, Allahabad 211002, Uttar Pradesh, India
关键词
Basic ionic liquid ([bmImOH]); Isocoumarin; Heterocycle Green Protocol; Ambient conditions; ALPHA-PYRONES; DERIVATIVES; ANTIFUNGAL; ANNULATION;
D O I
10.1016/j.catcom.2014.06.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Efficient and environmentally benign heterocyclization of o-halobenzoic acid and alkyne has been developed using [bmIm]OH as green catalyst. This methodology offers a metal and base free approach and is endowed with mild reaction conditions, high yields and better functional group tolerating ability. The recyclability and reuse of [bmIm]OH add the methodology a wide scope. (C) 2014 Elsevier B.V. All rights reserved.
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页码:70 / 73
页数:4
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