Synthesis of new macrocyclic aminomethylphosphines based on 4,4′-diaminodiphenylmethane and its derivatives

被引：20
|
作者：
Kuznetsov, RM [1 ]
Balueva, AS [1 ]
Litvinov, IA [1 ]
Gubaidullin, AT [1 ]
Nikonov, GN [1 ]
Karasik, AA [1 ]
Sinyashin, OG [1 ]
机构：
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 01期
关键词：
macrocyclic aminomethylphosphines; X-ray diffraction analysis; 4,4 '-bis(hydroxymethyl)phenylphosphine; diaminodiphenylmethane;
D O I：
10.1023/A:1015086419302
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of bis(hydroxymethyl)phenylphosphine with 4,4'-diaminodiphenylmethane in DMF afforded 1,1',5,5'-bis[metylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) (1) whose structure was established by X-ray diffraction analysis. Sulfurization and oxidation of macrocyclic tetraphosphine 1 gave rise to products 2 and 3, respectively, compound 3 being obtained as a stable hexahydrate. The reaction of bis(hydroxymethyl)phenylphosphine with bis(4-N-methylaminophenyl)methane in DMF followed by sulfurization yielded monocyclic bis{methylenedi[p-phenylene(N-methyl)amino-methyl]}di(P-phenyl)phosphine sulfide (4).
引用
收藏
页码：151 / 156
页数：6
相关论文
共 50 条
  • [1] Synthesis of new macrocyclic aminomethylphosphines based on 4,4"-diaminodiphenylmethane and its derivatives
    R. M. Kuznetsov
    A. S. Balueva
    I. A. Litvinov
    A. T. Gubaidullin
    G. N. Nikonov
    A. A. Karasik
    O. G. Sinyashin
    Russian Chemical Bulletin, 2002, 51 : 151 - 156
  • [2] SYNTHESIS AND PROPERTIES OF POLYCARBAMIDES BASED ON 4,4'-DIAMINODIPHENYLMETHANE DERIVATIVES
    KOTON, MM
    GLUKHOV, NA
    MIRONOVA, EA
    SHCHERBAKOVA, LM
    SAZANOV, YN
    LAYUS, LA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1978, 20 (11): : 847 - 850
  • [3] POLYAMIDOIMIDES ON BASIS OF 4,4'-DIAMINODIPHENYLMETHANE DERIVATIVES
    GUSINSKAYA, VA
    KOTON, MM
    BATRAKOVA, TV
    ROMASHKOVA, KA
    SHCHERBAKOVA, LM
    GLUKHOV, NA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1977, 19 (09): : 670 - 671
  • [4] STUDY AND MODELING 4,4′-DIAMINODIPHENYLMETHANE SYNTHESIS
    Menshutina, N., V
    Lebedev, I., V
    Lebedev, E. A.
    Dashkin, R. R.
    Shishanov, M., V
    Burdeyniy, M. L.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2021, 64 (04): : 100 - 103
  • [5] Synthesis and characterization of 4,4′,-diaminodiphenylmethane Schiff bases
    Biricik, Nermin
    Kayan, Cezmi
    ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (03) : 2369 - 2373
  • [6] Synthesis and crystal structure of a new organic compound: Bis(4,4′-diaminodiphenylmethane) (4,4′-diammoniodiphenylmethane) dichloride monohydrate
    W. Wamani
    M. Belhouchet
    T. Mhiri
    Crystallography Reports, 2013, 58 : 111 - 114
  • [7] Synthesis and crystal structure of a new organic compound: Bis(4,4′-diaminodiphenylmethane) (4,4′-diammoniodiphenylmethane) dichloride monohydrate
    Wamani, W.
    Belhouchet, M.
    Mhiri, T.
    CRYSTALLOGRAPHY REPORTS, 2013, 58 (01) : 111 - 114
  • [8] CANCEROGENIC EFFECT OF 4,4'-DIAMINODIPHENYLMETHANE AND 2,4'-DIAMINODIPHENYLMETHANE
    STEINHOFF, D
    GRUNDMANN, E
    NATURWISSENSCHAFTEN, 1970, 57 (05) : 247 - +
  • [9] Carbon Dot Initiated Synthesis of Poly(4,4′-diaminodiphenylmethane) and Its Methylene Blue Adsorption
    Maruthapandi, Moorthy
    Kumar, Vijay Bhooshan
    Gedanken, Aharon
    ACS OMEGA, 2018, 3 (06): : 7061 - 7068
  • [10] EPOXY-RESIN BASED ON 4,4'-DIHYDROXYDIPHENYLSULFONE .1. SYNTHESIS AND REACTION-KINETICS WITH 4,4'-DIAMINODIPHENYLMETHANE AND 4,4'-DIAMINODIPHENYLSULFONE
    SYKORA, V
    SPACEK, V
    DOBAS, I
    JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 54 (10) : 1463 - 1467
12345