The structure and phase behavior of electrodeposited halides on single-crystal metal surfaces

被引：60
|
作者：
Ocko, BM
Magnussen, OM
Wang, JX
Adzic, RR
Wandlowski, T
机构：
[1] BROOKHAVEN NATL LAB, DEPT APPL SCI, DIV CHEM SCI, UPTON, NY 11790 USA
[2] UNIV ULM, DEPT ELECTROCHEM, D-89069 ULM, GERMANY
来源：
PHYSICA B-CONDENSED MATTER | 1996年 / 221卷 / 1-4期
关键词：
D O I：
10.1016/0921-4526(95)00932-9
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Synchrotron X-ray scattering results of halide monolayers of bromide and iodide on single-crystal electrodes are presented. Both commensurate and incommensurate structures are observed. The incommensurate structures electrocompress with increasing potential. The relative roles of the halide-halide and the substrate-halide interactions are discussed for iodide on Au(1 1 1), Ag(1 1 1), and Pt(1 1 1) and for bromide on Au(1 1 1), Ag(1 1 1) and Au(1 0 0).
引用
收藏
页码：238 / 244
页数：7
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