Synthesis and crystal structure of complex Cu(C15H12N2O3)(C5H5N)

被引：0

作者：

Chen, XH ^{[1
]}

Liu, SX ^{[1
]}

机构：

[1] Fuzhou Univ, Cent Lab, Fuzhou 350002, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 06期

关键词：

copper complex; hydrazone N-substituted-salicyl Schiff ligand crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title coordination compound with N-substituted-salicyl Schiff ligand, Cu (C15H12N2O3)(C5H5N), has been synthesized. The coordination compound crystallizes in orthorhombic system, space group Pbca with a=2.037 62(7) nm, b=0.69845(2)nm, c=2.50876(9)nm, V=3.5704(2) nm(3), Z=8, F(000)=1 688, D-c=1.529 g.cm(-3), M-r=410.91, mu= 1.250 mm(-1), R=0.031 3 and wR=0.077 0. In the coordination compound, one phenolate oxygen, one carbonyl oxygen and one hydrazine nitrogen atom from the dianionic ligand N-salicylaldehyde-N'-(4-methoxybenzoyl) hydrazone and one pyridine nitrogen atom coordinate to Cu(II) ion, forming a distorted square plane.

引用

页码：668 / 670

页数：3

共 14 条

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