Copper(II) SBA-15: A reusable catalyst for azide-alkyne cycloaddition

被引：41

作者：

Jlalia, Ibtissem ^{[1
]}

Gallier, Florian ^{[2
]}

Brodie-Linder, Nancy ^{[2
,3
]}

Uziel, Jacques ^{[2
]}

Auge, Jacques ^{[2
]}

Lubin-Germain, Nadege ^{[2
]}

机构：

[1] INRAP, Lab Subst Nat, Sidi Thabet 2020, Tunisia

[2] Univ Cergy Pontoise, Lab Synthese Organ Select & Chim BioOrgan, EA 4505, F-95000 Cergy Pontoise, France

[3] CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2014年 / 393卷

关键词：

Click chemistry; Mesoporous materials; Cycloaddition; Heterogeneous catalysis; Copper(II); ONE-POT SYNTHESIS; HETEROGENEOUS NANO CATALYST; CU-II-HYDROTALCITE; 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY; ORGANIC AZIDES; HUISGEN CYCLOADDITION; TERMINAL ALKYNES; SUPPORTED CATALYST; HIGHLY EFFICIENT;

D O I：

10.1016/j.molcata.2014.06.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The azide-alkyne cycloaddition reaction was investigated under catalytic conditions involving a copper(II) loaded silica based mesoporous material. Cu(II) SBA-15 demonstrated a high catalytic effect in 1,4-triazoles synthesis in organic. No additives such as a base or a reductant are required. Quantitative yields were obtained and a mere filtration of the mesoporous material which retains copper(II) allows the recovery of the catalyst. In addition, up to 5 times recycling of the catalyst was achieved without loss of the activity affording 1,4-triazoles in a yield up to 98%. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：56 / 61

页数：6

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