Iron-Mediated Cleavage of C-C Bonds in Vicinal Tricarbonyl Compounds in Water

被引：53
|
作者：
Mecinovic, Jasmin [1 ]
Hamed, Refaat B. [1 ]
Schofield, Christopher J. [1 ]
机构：
[1] Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 15期
基金：
英国惠康基金; 英国生物技术与生命科学研究理事会;
关键词：
C-C cleavage; homogeneous catalysis; iron; redox chemistry; tricarbonyl compounds; L-ASCORBIC-ACID; CHEMISTRY; OXIDATION; NINHYDRIN; PLANTS; OXYGEN;
D O I：
10.1002/anie.200806296
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three of a kind: Vicinal tricarbonyl compounds undergo C-C cleavage mediated by ferric ions (see scheme). The observed cleavage of ninhydrin and dehydroascorbic acid has relevance for amino acid detection and the metabolism of vitamin C. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2796 / 2800
页数：5
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