Synthesis of diesel and jet fuel range alkanes with furfural and ketones from lignocellulose under solvent free conditions

被引：89
|
作者：
Yang, Jinfan [1 ,2 ]
Li, Ning [1 ]
Li, Shanshan [1 ,2 ]
Wang, Wentao [1 ]
Li, Lin [1 ]
Wang, Aiqin [1 ]
Wang, Xiaodong [1 ]
Cong, Yu [1 ]
Zhang, Tao [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
GREEN CHEMISTRY | 2014年 / 16卷 / 12期
关键词：
POT CATALYTIC CONVERSION; HIGH-QUALITY DIESEL; LIQUID ALKANES; PHASE HYDROGENATION; ALDOL-CONDENSATION; RENEWABLE DIESEL; ETHYLENE-GLYCOL; BIOMASS; CELLULOSE; HYDRODEOXYGENATION;
D O I：
10.1039/c4gc01314j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Under solvent-free conditions, C9-C12 alkanes were first synthesized at high overall carbon yield (similar to 80%) by the solid base catalyzed aldol condensation of furfural with 2-pentanone (or a mixture of 2-pentanone and 2-heptanone) from lignocellulose, followed by direct hydrodeoxygenation over Pd loaded solid acid catalysts at 533 K.
引用
收藏
页码：4879 / 4884
页数：6
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