Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2',3'-D) pyrrole derivative

被引：6

作者：

Kivrak, Arif ^{[1
]}

Yildiz, Huseyin Bekir ^{[2
,3
]}

Gokyer, Selahattin ^{[1
]}

Bezgin Carbas, Buket ^{[4
,5
]}

机构：

[1] Van Yuzuncu Yil Univ, Fac Sci, Dept Chem, Van, Turkey

[2] Karatay Univ, Dept Mat Sci & Nanotechnol Engn, KTO, Karatay, Konya, Turkey

[3] FELSIM Inc, Biotechnol Res Lab, Selcuklu, Konya, Turkey

[4] Karamanoglu Mehmetbey Univ, Dept Energy Syst Engn, Karaman, Turkey

[5] Karamanoglu Mehmetbey Univ, Conduct Polymers & Energy Applicat Lab, Karaman, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2018年 / 42卷 / 02期

关键词：

Conjugated polymers; dithieno; (3; 2-B:2'; 3'-D); pyrrole; electrochromism; electrochemistry; optical properties; LOW-BANDGAP; COPOLYMERS; POLYMERS; ACCEPTOR; ADSORPTION;

D O I：

10.3906/kim-1709-33

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel alkoxy-bridged dithieno (3, 2-B:2',3'-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2',3'-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The effects of alkoxy bridge in the structure on the electrochemical and spectroelectro-chemical properties of the polymer were also investigated in detail. The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.

引用

页码：439 / +

页数：10

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