An original 3D coordination polymer constructed from trinuclear nodes and tetracarboxylato spacers

被引：3

作者：

Dinca, Alina S. ^{[1
]}

Dogaru, Andreea ^{[2
]}

Ion, Adrian E. ^{[1
,2
]}

Nica, Simona ^{[2
]}

Dumitrescu, Dan ^{[3
]}

Shova, Sergiu ^{[4
]}

Lloret, Francesc ^{[5
]}

Julve, Miguel ^{[5
]}

Andruh, Marius ^{[1
]}

机构：

[1] Univ Bucharest, Inorgan Chem Lab, Fac Chem, Str Dumbrava Rosie 23, Bucharest, Romania

[2] Romanian Acad, CD Nenitzescu Inst Organ Chem, Splaiul Independentei 202B, Bucharest 060023, Romania

[3] Elettra Sincrotrone Trieste SCpA, Str Statale 14 Km 163,5 Area Sci Pk, I-34149 Trieste, Italy

[4] Romanian Acad, Petru Poni Inst Macromol Chem, Grigore Ghica Voda Alley 41A, Iasi 700847, Romania

[5] Univ Valencia, Fac Quim, Dept Quim Inorgan, Inst Ciencia Mol, C Catedrat Jose Beltran 2, Valencia 46980, Spain

来源：

CRYSTENGCOMM | 2021年 / 23卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORKS; BUILDING UNITS; DIVERSITY; SORPTION; BLOCKS;

D O I：

10.1039/d0ce01667e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 3D coordination polymer,( infinity)(3)[{Cu-3(felden)}(4)(btec)(3)]center dot 17H(2)O, has been assembled using cationic trigonal nodes, [Cu-3(II)(felden)](3+), generated by a tricompartmental ligand, H(3)felden, which results from the Schiff condensation reaction between 2,4,6-triformylphloroglucinol and N,N-dimethylethylenediamine. The tetraanion of the 1,2,4,5-benzenetetracaboxylic acid (H(4)btec) was employed as a spacer. The structure of 1 shows Large icosahedral cavities and channels and the magnetic interaction between the copper(II) ions within the triangles is weak and antiferromagnetic.

引用

页码：1332 / 1335

页数：4

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