Research progress of iron-based catalysts for selective oligomerization of ethylene

被引:14
|
作者
Wang, Mingzhi [1 ]
Wu, Wei [1 ]
Wang, Xu [2 ]
Huang, Xing [3 ]
Nai, Yongning [1 ]
Wei, Xueying [1 ]
Mao, Guoliang [1 ]
机构
[1] Northeast Petr Univ, Prov Key Lab Oil & Gas Chem Technol, Coll Chem & Chem Engn, Daqing 163318, Peoples R China
[2] Anhui Jianzhu Univ, Sch Foreign Languages, Hefei, Peoples R China
[3] Northeast Petr Univ, Sch Civil Engn & Architecture, Daqing, Peoples R China
基金
中国国家自然科学基金;
关键词
SUBSTITUTED BIS(ARYLIMINO)PYRIDINE LIGANDS; HYPERBRANCHED SALICYLALDIMINE LIGANDS; COBALT BIS(IMINO)PYRIDINE CATALYSTS; CHROMIUM-BASED CATALYSTS; HIGHLY-ACTIVE CATALYSTS; SINGLE-SITE CATALYSTS; 2,6-BIS(IMINO)PYRIDYL IRON; ALPHA-OLEFINS; METAL-COMPLEXES; II COMPLEXES;
D O I
10.1039/d0ra07558b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Linear alpha-olefins are widely used as raw materials in the chemical industry. Selective ethylene oligomerization is an important development direction of the linear alpha-olefin production process. Iron-based catalysts have become a research hotspot in selective ethylene oligomerization due to their advantages like high activity, high selectivity and convenience of adjusting their ligand structures. In this paper, the research progress of catalysts for selective oligomerization of ethylene was reviewed in terms of the cocatalysts, ligand structure, and immobilization of homogeneous catalysts.
引用
收藏
页码:43640 / 43652
页数:13
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