MOF-Derived Porous ZnO/ZnFe2O4/C Octahedra with Hollow Interiors for High-Rate Lithium-Ion Batteries

被引:706
|
作者
Zou, Feng [1 ]
Hu, Xianluo [1 ]
Li, Zhen [1 ]
Qie, Long [1 ]
Hu, Chenchen [1 ]
Zeng, Rui [1 ]
Jiang, Yan [1 ]
Huang, Yunhui [1 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China
关键词
hollow structures; porous nanostructures; batteries; metal-organic frameworks; HIGH-PERFORMANCE ANODE; METAL-ORGANIC FRAMEWORKS; ENERGY-STORAGE; NANOPARTICLES; GRAPHENE; CAPACITY; OXIDES; COO;
D O I
10.1002/adma.201402322
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Graph Presented) Novel porous ZnO/ZnFe2O4/C octahedra with hollow interiors are fabricated by a facile self-sacrificing template method involving the refluxing synthesis of hollow, metal-organic framework octahedra in solution and subsequent thermal annealing in N2. When evaluated as an anode material for lithiumion batteries, these porous hollow ZnO/ZnFe2O4/C octahedra exhibit significantly enhanced electrochemical performances with high rate capability, high capacity, and excellent cycling stability. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6622 / 6628
页数:7
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