Infinite three-dimensional coordination polymers:: Synthesis and structures of [Cd (4,4′-bpy)2 (H2O)2]n (pic)2n, [Zn (4,4′-bpy)2 (H2O)2]n-(pic)2n (H2O)2n, and [Zn (4,4′-bpy)2 (H2O)2]n (4,4′-bpy)n (H2O)n (pic)2n

被引：0
|
作者：
Liang, FP
Chen, ZL
Hu, RX
Liang, H
Zhou, ZW
机构：
[1] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China
[2] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2000年 / 11卷 / 04期
关键词：
clathration; 4,4 '-bipyridine; picric anion; three-dimensional network;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three Complexes of the formula [ Cd (4.4'-bpy)(2) (H2O2) ](n) (pic)(2n) (1). [ Zn (4.4'-bpy)(2) (H2O)(2), ](n)-(pic)(2n) (H2O)(2n) (2) and [ Zn ( 4. 4'-bpy)(2) (H2O)(2) ](n) (4.4'-bpy)(n) (pic)(2n) (H2O)(n) (3) (4.4'-bpy = 4.4'.-bipyridine: pic = picric anion) have been synthesized and characterized by elemental analysis and single-crystal x-ray diffraction. They all have infinite three-dimensional network structure, crystallizing in the monoclinic space group C2/c (1)and Cc (2,3).
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页码：369 / 372
页数：4
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