An Iron Complex with an Unsupported Fe-Fe Bond

被引：9
|
作者：
Murillo, Carlos A. [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 28期
关键词：
iron; metal-metal interaction; structure elucidation; synthetic methods; unsupported bonds; METAL; LIGANDS;
D O I：
10.1002/anie.200901802
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Full metal bonding: The reduction of a six-coordinate, mononuclear Werner-type iron(II) complex (see scheme) resulted in the isolation of a compound with an extraordinarily rare, unsupported Fe-Fe bond having an experimental Fe-Fe distance of 2.6869(6) Å and a calculated bond order of 0.5. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5076 / 5077
页数：2
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