Oxidation of benzyl alcohol with dioxygen catalyzed by an inorganic polymer-platinum complex

被引：0
|
作者：
Yang, XT [1 ]
Li, Y [1 ]
Huang, MY [1 ]
Jiang, YY [1 ]
机构：
[1] ACAD SINICA,INST CHEM,BEIJING 100080,PEOPLES R CHINA
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 1996年 / 7卷 / 01期
关键词：
oxygenation; benzyl alcohol; polytitanzane-platinum complex;
D O I：
10.1002/(SICI)1099-1581(199601)7:1<47::AID-PAT485>3.0.CO;2-O
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An inorganic polymer-platinum complex, magnesia supported polytitanzane-platinum complex (MgO-Ti-N-Pt), was prepared and used to catalyze the oxygenation of benzyl alcohol. It was found that this kind of catalyst has great activity and stability in the reaction. The objective product (benzaldehyde) was obtained in 100% yield in 6 hr under a moderate reaction temperature and atmospheric oxygen pressure. This inorganic polymer complex was also very stable during the reaction.
引用
收藏
页码：47 / 49
页数：3
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