Homofugality:: A new reactivity index describing the leaving group ability in homolytic substitution reactions

被引：16

作者：

Guerra, Doris

Castillo, Raquel

Andres, J.

Fuentealba, P.

Aizman, A.

Contreras, R.

机构：

[1] Univ Andres Bello, Dept Ciencias Quim, Fac Ecol & Recursos Nat, Santiago, Chile

[2] Univ Jaime 1, Dept Ciencias Expt, Castellon de La Plana, Spain

[3] Univ Chile, Fac Ciencias, Dept Fis, Santiago, Chile

[4] Univ Chile, Fac Ciencias, Dept Quim, Santiago, Chile

[5] Univ Tecn Federico Santa Maria, Dept Quim, Valparaiso, Chile

来源：

CHEMICAL PHYSICS LETTERS | 2006年 / 424卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2006.04.092

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank the leaving group ability of radical fragments present in homolytic substitution reactions. The model is validated for a series of S(H)2 processes involving organometallic systems. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：437 / 442

页数：6

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