Influence of alkyl chain length on the mesomorphism of 5-S-alkyl-5-thiopentonolactones and 5-S-alkyl-5-thiopentitols

被引：4

作者：

Stasik, Imane ^{[1
,2
]}

Gottis, Sebastien ^{[1
,2
]}

Falentin-Daudre, Celine ^{[1
,2
]}

Meyer, Claire ^{[3
]}

机构：

[1] CNRS FRE 3517, Lab Glycochim Antimicrobiens & Agroressources LG2, F-80039 Amiens, France

[2] Inst Chim Picardie FR 3085, F-80039 Amiens, France

[3] Lab Phys Syst Complexes, EA 4663, F-80039 Amiens, France

来源：

CARBOHYDRATE RESEARCH | 2014年 / 392卷

关键词：

S-Alkylthiopentonolactones; S-Alkylthiopentitols; Liquid crystals; Thermotropy; Lyotropy; Odd or even methylene group number; LIQUID-CRYSTALLINE PROPERTIES; S-ALKYLTHIOPENTONOLACTONES; AMPHIPHILIC PROPERTIES; HOMOLOGOUS SERIES; BEHAVIOR; SURFACTANTS; DERIVATIVES; GLYCOLIPIDS; MESOGENS; PHASES;

D O I：

10.1016/j.carres.2014.04.008

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Mesomorphic properties of S-alkylthiopentonolactones (n-ribono, D-arabinono and D-xylono) and corresponding alditol derivatives with the general formula Su SR (R = CnH2n+1; n = 5-12) are studied. It was shown that the thermotropic and lyotropic phase transition temperatures are influenced by the following structural parameters: alkyl chain length, cyclic or acyclic Su structure and alditol conformation. Besides, it seems that n parity affects thermotropic phase transition temperatures. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：31 / 39

页数：9

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