Interaction of water with GeCl4,SnCl4, and ASCl3

被引：6
|
作者：
Efremov, VA
Potolokov, VN
Nikolashin, SV
Fedorov, VA
机构：
[1] Mendeleev Univ Chem Technol, Moscow 125820, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
INORGANIC MATERIALS | 2002年 / 38卷 / 08期
关键词：
Spectroscopy; Chloride; Hydrolysis; Inorganic Chemistry; Water Concentration;
D O I：
10.1023/A:1019791114256
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The interaction of water with GeCl4, SnCl4, and AsCl3 was studied by IR spectroscopy. The results demonstrate that these chlorides contain molecular water in monomeric form. At water concentrations above 10(-2) mol/l, GeCl4 also contains H3O+ ions, The mechanisms of GeCl4 and AsCl3 hydrolysis were studied over a wide range of water concentrations.
引用
收藏
页码：837 / 846
页数：10
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