Molecular Self-Assembly of Cyclic Dipeptide Derivatives and Their Applications

被引：92
|
作者：
Manchineella, Shivaprasad [1 ]
Govindaraju, T. [1 ]
机构：
[1] JNCASR, Bioorgan Chem Lab, New Chem Unit, Bengaluru 560064, Karnataka, India
来源：
CHEMPLUSCHEM | 2017年 / 82卷 / 01期
关键词：
biomaterials; bionanotechnology; chiral auxiliaries; cyclic dipeptides; self-assembly; MASS ORGANIC GELATORS; PEPTIDE NANOTUBES; BUILDING-BLOCKS; SUPRAMOLECULAR HYDROGELS; DIPHENYLALANINE PEPTIDE; MECHANICAL-PROPERTIES; WEIGHT GELATORS; DRUG-DELIVERY; SOFT MATTER; AMINO-ACIDS;
D O I：
10.1002/cplu.201600450
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cyclic dipeptides (CDPs) are heterocyclic 2,5-diketopiperazines with exceptional structural rigidity, enzymatic stability, and biological activity, exhibiting a substantial tendency to take part in intermolecular interactions. Strong intermolecular interactions driven by unique hydrogen bonding patterns render CDPs with a high propensity to undergo molecular self-assembly. In this Review, the aim is to provide a comprehensive summary of design strategies used to engineer the molecular self-assembly of CDPs into functional nano- and micro-architectures and molecular gels with potential applications in biomedical and materials engineering fields.
引用
收藏
页码：88 / 106
页数：19
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