Luminescence spectra of Cs2NaLuBr6:Eu3+ crystal

被引:0
|
作者
Dushin, RB [1 ]
Barbanel', YA [1 ]
Kolin, VV [1 ]
Kotlin, VP [1 ]
Nekhoroshkov, SN [1 ]
Chudnovskaya, GP [1 ]
机构
[1] Khlopin Radium Inst, Res & Prod Assoc, St Petersburg, Russia
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中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Luminescence spectra of Cs2NaLuBr6:Eu3+ crystal (1 mol% Eu) in the 400-600 nm range at 12-300 K are obtained. The vibronic pattern of the electronic transitions of the EuBr63- moiety in the crystal lattice is analyzed, and the transitions observed are assigned. Fifteen excited electronic sublevels of the EuBr63- complex are localized. Low-temperature splitting is found for some transitions; the splittings decrease with rising temperature and completely disappear at 80 K.
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页码:53 / 60
页数:8
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