Transition-Metal-Free Catalytic Reduction of Carbon Dioxide

被引：108
|
作者：
Fontaine, Frederic-Georges [1 ]
Courtemanche, Marc-Andre [1 ]
Legare, Marc-Andre [1 ]
机构：
[1] Univ Laval, Dept Chim, Quebec City, PQ G1V 0A6, Canada
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 11期
基金：
加拿大自然科学与工程研究理事会;
关键词：
carbon dioxide; frustrated Lewis pairs; main group elements; organocatalysis; reduction; FRUSTRATED LEWIS PAIRS; FREE HYDROGEN ACTIVATION; N-HETEROCYCLIC CARBENE; PHOSPHINE-BORANE; CO2; REDUCTION; HOMOGENEOUS HYDROGENATION; METHANOL; COMPLEXES; FIXATION; CONVERSION;
D O I：
10.1002/chem.201304376
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-free systems, including frustrated Lewis pairs (FLPs) have been shown to bind CO2. By reducing the Lewis acidity and basicity of the ambiphilic system, it is possible to generate active catalysts for the deoxygenative hydroboration of carbon dioxide to methanol derivatives with conversion rates comparable to those of transition-metal-based catalysts.
引用
收藏
页码：2990 / 2996
页数：7
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