Chiral porous organic frameworks for asymmetric heterogeneous catalysis and gas chromatographic separation

被引：94
|
作者：
Dong, Jinqiao [1 ,2 ]
Liu, Yan [1 ,2 ]
Cui, Yong [1 ,2 ,3 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 95期
关键词：
CONJUGATED MICROPOROUS POLYMERS; AROMATIC FRAMEWORK; RESOLUTION; ARYLATION; HYDROGEN; LIGANDS; DESIGN; ADSORPTION; BINDING; METHANE;
D O I：
10.1039/c4cc07648f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three chiral robust diene-based porous organic frameworks (POFs) are prepared. POF-1 is shown to be an efficient heterogeneous catalyst after metallation for asymmetric conjugation addition with up to 93% ee, and it can also function as a new chiral stationary phase for gas chromatographic separation of racemates.
引用
收藏
页码：14949 / 14952
页数：4
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